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NdCl_3-MgCl_2-LiCl系液相限的研究

郑朝贵 , 靳军 , 叶于浦

金属学报

本文借助于DTA研究了NdCl_3-MgCl_2-LiCl三元体系的液相限。发现:本体系内有对应于NdCl_3和α-固溶体(MgCl_2,LiCl)的两个液相面和一条带有最低点的二次结晶线,其最低点M的组成与温度为:68.5wt-%NdCl_3,2.7wt-%MgCl_2,28.8wt-%LiCl;441℃。

关键词: NdCl_3 , NdCl_3-MgCl_2-LiCl , ternary system , liquidus

LIQUIDUS OF NdCl_3-MgCl_2-LiCl SYSTEM

ZHENG Chaogui JIN Jun YE Yupu Department of Chemistry , Peking University , Beijing , China Dept.of Chemistry , Peking University , Beijing , China

金属学报(英文版)

The liquidus of ternary system NdCl_3-MgCl_2-LiCl has been determined by means of DTA.It was found that there are two surfaces corresponding to the primary crystallization of NdCl_3 and α-(MgCl_2,LiCl)respectively,and a univariant line related to the secondary crystallization with a minimum M(68.5 wt-% NdCl_3,2.7 wt-% MgCl_2,28.8 wt-% LiCl_2 441℃)in the system.

关键词: NdCl_3 , null , null , null

A New Model for Predicting Ternary Thermodynamic Properties of Solution Phase and Its Application

Zhiyu QIAO Xianran XING Shuzhen DUAN University of Science and Technology Beijing , Beijing , 100083 , ChinaChaogui ZHENG Beijing University , Beijing , 100871 , China

材料科学技术(英)

A new geometric asymmetric model for predicting the thermodynamic properties of ternary system from three sub-binaries is presented in this paper.Its analytical expression with good calculating ac- curacy is most simple in all asymmetric models.The new model was applied to predict the enthalpies of mixing of the Bi-Ga-Sn.Au-Ag-Sn and NaCl-KCl-CaCl_2 ternary systems which were in good agreements with experimental data.Based on thermodynamic principles,the importance of the choice of asymmetric component is also discussed.The error analysis indicates that in the case of judging the asymmetric component in ternary system according to the thermodynamic criterion the deviation is minimum.It is of great significance to improve the calculating accuracy for predicting thermodynamic properties of ternary solution phase from the sub-binary ones.

关键词: thermodynamic properties , null , null

Bi-Pb-Tl三元系相图

车广灿 , M.ELLNER

金属学报

用室温、高温X射线衍射及淬火的方法,测定了Bi-Pb-Tl三元系25℃的等温截面及该体系中的相结构。

关键词: 三元系相图 , phase diagram , Bi-Pb-Tl system , X-ray diffraction

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